Although a photon has zero rest mass, it carries momentum. According to Einstein's theory and Planck's relation, the momentum of a photon is:
where is Planck's constant, is the frequency, is the speed of light, and is the wavelength. This shows that a photon's momentum is inversely proportional to its wavelength.
This result is crucial: it means light can exert a radiation pressure and can transfer momentum to matter — a purely particle-like behaviour.
In 1923, Arthur H. Compton directed a beam of X-rays at a graphite (carbon) target and analysed the scattered X-rays. He found that the scattered X-rays had a longer wavelength (lower energy) than the incident X-rays. This phenomenon is called the Compton Effect.
Compton explained this by treating the X-ray photon as a particle that collides elastically with a free (loosely bound) electron in the target, similar to a billiard-ball collision:
This experiment provided direct evidence that photons carry momentum and behave as particles.
Applying conservation of energy and conservation of momentum to the photon–electron collision, Compton derived:
| Symbol | Meaning |
|---|---|
| Wavelength of scattered photon | |
| Wavelength of incident photon | |
| Compton shift (always ) | |
| Planck's constant ( J·s) | |
| Rest mass of electron ( kg) | |
| Speed of light ( m/s) | |
| Angle of scattering |
The constant is called the Compton wavelength of the electron:
| Scattering Angle | ||
|---|---|---|
| (forward) | (no shift) | |
| nm | ||
| (backscatter) | nm (maximum) |
The Compton shift nm is fixed regardless of the incident wavelength. For visible light (– nm), the fractional change:
This is negligibly small and undetectable. For X-rays ( nm), the fractional shift is significant (~2%), making it observable.
Pair production is the process in which a high-energy gamma-ray photon () is converted into an electron–positron pair in the vicinity of a nucleus:
Pair annihilation is the reverse of pair production. When an electron () meets a positron (), they annihilate each other and produce two gamma-ray photons:
| Process | Reactant | Product | Energy Condition |
|---|---|---|---|
| Pair Production | photon | MeV | |
| Pair Annihilation | Each MeV |