The resistance of a material is a measure of its opposition to the flow of electric current. This property is not constant; it is significantly influenced by the material's temperature. Understanding this relationship is crucial for designing and operating electrical and electronic components in various thermal environments.

For many materials, especially metals, the change in resistance with temperature is approximately linear over a certain range. This relationship is described by the temperature coefficient of resistance ().
Definition: The temperature coefficient of resistance is the fractional change in resistance per unit change in temperature:
The formula to calculate the resistance () at a certain temperature () is:
Where:
The effect of temperature on resistance varies greatly depending on the type of material.
| Material Type | Resistance Behavior with Increasing Temperature | Reason |
|---|---|---|
| Metals (Conductors) | Increases (Positive ) | Increased thermal vibrations of lattice atoms cause more frequent collisions with free electrons, impeding their flow. |
| Semiconductors | Decreases (Negative ) | Higher temperature frees more charge carriers (electrons and holes), increasing conductivity. |
| Insulators | Very high; decreases slightly | Similar mechanism to semiconductors but requires much more energy to free charge carriers. |
| Electrolytes | Decreases | Higher temperature increases ion mobility in solution, allowing easier current flow. |
| Alloys | Increases very slightly | Designed to have a very low , making them stable for precision resistors. |
The resistance () of a specific conductor depends on both its material and its physical dimensions.
Where:
Example Resistivity Values at 20°C:
| Material | Resistivity () () | Classification |
|---|---|---|
| Copper | Conductor | |
| Silicon | Semiconductor | |
| Quartz (Fused) | Insulator |
Superconductors: Materials whose resistance drops to exactly zero below a critical temperature. In this state, they conduct electricity with no energy loss.
Thermistors: Semiconductor-based resistors with a large and predictable change in resistance with temperature, used in temperature sensors and control circuits.